Let's first find the number of atoms in a sample of pitchblende:
"N=\\dfrac{mN_A}{M_m},""N=\\dfrac{50\\ kg\\times6.022\\times10^{23}\\ mol^{-1}}{238.4\\times10^{-3}\\ \\dfrac{kg}{mol}}=1.263\\times10^{26}\\ atoms."Let's use the formula for radioactive decay:
"N=N_0e^{-\\lambda t},""\\dfrac{N}{N_0}=e^{-\\lambda t},""ln(\\dfrac{N}{N_0})=ln(e^{-\\dfrac{0.693}{T_{1\/2}}t}),""ln(\\dfrac{N}{N_0})=-\\dfrac{0.693}{T_{1\/2}}t,""t=(\\dfrac{ln(\\dfrac{N}{N_0})}{-0.693})T_{1\/2},""t=(\\dfrac{ln(\\dfrac{1.263\\times10^{26}\\ atoms}{1.263\\times10^{26}\\ atoms})}{-0.693})\\times4.5\\times10^9\\ yr=3.1\\times10^7\\ yr."
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