If the ray of light is directed at an angle to the surface, and the angle is not 90° to the surface (or 0° to the perpendicular to the surface), the ray changes direction each time it crosses the air/glass boundary because the refraction indexes of air and glass are different, and according to Snell's law, the ray of light will experience refraction.
If the angle to the perpendicular to the surface is 0°, sine of 0° is 0 and no changes in direction occur.
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