Protons are made of two Up and one Down quark. The neutron is made of two Down and one Up quark. The Up quarks have a 2/3 positive charge and the Down has a 1/3 negative charge. Fractional charges are a pretty funny concept, but remember we (humans) made up the unit of charge that a proton has, so its very possible that there could be a smaller division of charge. If you add those charges you will see that sum is positive one for the proton and 0 for the neutron.
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