We can measure the pressure in cm because we will express pressures in terms of mercury and replace volumes of the trapped air with heights because the tube has uniform cross-section.
With the closed end down and "volume" of 30 cm, the pressure inside is
where "h_m" is pressure of the mercury and "h_a" is the pressure of the atmosphere.
1) When the tube is held horizontally, the mercury is just a barrier, trapped air pressure equals the atmospheric ("P_2=P_0" or "h_2=h_0"), the temperature is constant, according to Boyle's law:
2) When the tube is again turned 90°, the atmosphere pushes the mercury upward, the mercury tries to flow downward because of gravity:
Therefore, the "volume" or height "V_3" of the air in the tube is:
"P_3V_3=P_1V_1,\\\\\nV_3=\\frac{P_1V_1}{P_3}=\\frac{h(h_0+h_m)}{h_0-h_m}=\\frac{30(76+16)}{76-16}=46\\text{ cm}."
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