Solution.
a) "PV = nRT \\implies n = PV\/RT;"
"n = (1.55\\sdot 10^5 Pa\\sdot5m^3)\/(8.31 J\/mol K\\sdot350K) = 266.5mol;"
"T_c = PV\/nR;"
"Tc = (1.85\\sdot10^5 Pa\\sdot20m^3)\/(266.5mol\\sdot8.31J\/molK) = 167K;"
b)"W_Bc = 0; W_CA = (P_A + P_C)\/2\\sdot(V_C-V_A);"
"W_CA = (1.55\\sdot10^5 + 1.85\\sdot10^5)\/2\\sdot(20-5) =25.5\\sdot10^5J = 2.55MJ;"
c) "Q_BC = W_BC + \\Delta E_int; \\implies \\Delta E_int = Q_BC - W_BC;"
"\\Delta E_int = 5088660J;"
"Q_CA = W_CA + \\Delta E_int; \\implies \\Delta E_int = Q_CA - W_CA;"
"\\Delta E_int =-6937500 - 2.55\\sdot10^6 = 9.49\\sdot10^6J;"
d) "W_AB = -\\Delta E_int; W_AB = -5550000J = -5.5\\sdot10^6J;"
e) "W_ABC = W_AB + W_BC + W_CA;"
"W_ABCA = -5.5\\sdot10^6 + 0 + 2.55\\sdot10^6 = -2.95MJ;"
"Q_ABCA = Q_AB + Q_BC + Q_CA;"
"Q_ABCA = 0 + 5088660 -6937500 = -1848840J;"
"\\Delta E_int_ABCA =\\Delta E_int_AB + \\Delta E_int_BC + \\Delta E_int_CA;"
"\\Delta E_int_ABCA = -5550000 + 5088660 -6937500 = 3701160J ;"
Answer: a)"n = 266.5 mol; T_C = 167K;"
b) "W_BC = 0; W_CA = 2.55 MJ;"
c) "\\Delta E_int_BC = 5.088MJ; \\Delta E_int_CA = 9.49MJ;"
d) "W_AB = -5.5MJ;"
e)"W_ABCA = -2.95MJ;"
"Q_ABCA = -1.85MJ;"
"\\Delta"E_int_ABCa = 3.7MJ.
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