Condition for "m^{th}" interference maximum is "d sin \\theta = m \\lambda", where "d" is slit separation and "\\lambda" is the wavelength.
We are given grating "N = 14438\\frac{lines}{inch}", from where the slit separation is "d = \\frac{1}{N} = 6.926 inch= 1.759 \\cdot 10^{-6} m". The wavelength is "\\lambda = 8000A = 800nm".
Hence, for the first maximum, "\\sin \\theta = \\frac{\\lambda}{d} \\approx 0.455", which corresponds to "\\theta \\approx 27^{\\circ}".
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