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The potential energy of a system of two atoms is given by the expression, 𝐔 = −𝐀 𝐫 𝟑 + 𝐁 𝐫 𝟖 A stable molecule is formed with release of 10 eV of energy when the interatomic distance is 3 A°. Determine the force needed to dissociate this molecule into atoms and the interatomic distance at which the dissociation occurs


Consider the following differential dq=nCvdT+nRT/v dv where n and R are constants

a) Is the above dq an exact or inexact(show how you arrived to your conclusion by evaluating the appropriate partial differentials

b)Based on your answer in a) is the thermodynamic quantity q a path or state function?why?


For any thermodynamic equation of the state

"\\delta"H/"\\delta"P)T =V-T("\\delta" V/"\\delta" T)P derive an expression for ("\\delta" H/"\\delta" P) for the van der wall gas (P+an2/V2)(V-nb=nRT)


An audio speaker producing a steady sound at an outdoor concert is 18 ft away from you. If you move to a position where the speaker is 67 ft distant, by what factor will the amplitude of the sound change?



The mercury-in glass thermometer has the ice and steam pint as 6cm and 31cm respectively. Calculate the height of the Mercury when the temperature is 60°

The resistance 𝑅𝜃 of a particular resistance thermometer at a Celsius temperature 𝜃 as measured by a constant-volume gas thermometer is given by

𝑅𝜃 = 50.00 + 0.1700𝜃 + 3.00 × 10−4𝜃2.

Calculate the temperature as measured on the scale of the resistance thermometer which corresponds to a temperature of 60°𝐶 on the gas thermometer.


A cook puts 9.00 g of water in a 2.00-L pressure cooker that is then warmed to 500oC . What is the pressure inside the container? 

What is delta S, the change in entropy of ten moles of an ideal monatomic gas that is expanded slowly and isothermally at a temperature of 293K from a pressure of 2 atm to a pressure of 1 atm?

a) 57.6 J/K

b) 203.4 J/K

c) 21.7 J/K



Two systems have thermodynamic probabilities of 3.0 * 10^27 and 1.8 10*28 respectively calculate the entropies of the individual systems as well as their in composite systems and verify the boltzsmen relation

A Carnot engine has an efficiency of 50% when it sinks temperature is at 27 degree celcius calculate the change in source temperature for increasing its efficiency to 60%

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