Question

A particle of mass m moves in a three dimensional box with dimensions a , b , c . Calculate the

allowed energy values.
For a=b=c=L give the first five eigenvalues of the energy and the coresponding degenerate energy levels .


Hint:
Consider solution of this kind: Ψ(x , y , z)=Ψx (x)Ψy ( y )Ψ z(z ) with energy E and solve for
Ψx ,Ψy ,Ψz with energies Ex , Ey ,Ez where E=Ex+Ey+Ez

Answer 1

1

Question #84295, Physics / Molecular Physics | Thermodynamics |

A particle of mass $m$ moves in a three-dimensional box with dimensions $a$, $b$, $c$. Calculate the allowed energy values. For $a = b = c = L$ give the first five eigenvalues of the energy and the corresponding degenerate energy levels

Hint:

Consider solution of this kind: $\Psi(x, y, z) = \Psi(x)\Psi y(y)\Psi z(z)$ with energy $E$ and solve for $\Psi x, \Psi y, \Psi z$ with energies $Ex, Ey, Ez$ where $E = Ex + Ey + Ez$

Solution

The potential for the particle inside the box

$$V(\vec{r}) = 0$$

- $0 \leq x \leq L_x$

- $0 \leq y \leq L_y$

- $0 \leq z \leq L_z$

- $L_x < x < 0$

- $L_y < y < 0$

- $L_z < z < 0$

$r \rightarrow$ is the vector with all three components along the three axes of the 3-D box: $r = L_x x + L_y y + L_z z$. When the potential energy is infinite, then the wavefunction equals zero. When the potential energy is zero, then the wavefunction obeys the Time-Independent Schrodinger Equation

$$- \frac{\hbar^2}{2m} \nabla^2 \psi(r) + V(r) \psi(r) = E \psi(r)$$

Since we are dealing with a 3-dimensional figure, we need to add the 3 different axes into the Schrodinger equation:

$$\frac{\hbar^2}{2m} \left( \frac{d^2 \psi(r)}{dx^2} + \frac{d^2 \psi(r)}{dy^2} + \frac{d^2 \psi(r)}{dz^2} \right) - E \psi(r)$$

The easiest way in solving this partial differential equation is by having the wavefunction equal to a product of individual functions for each independent variable (e.g., the separation of variables technique):

$$\psi(x, y, z) = X(x)Y(y)Z(z)$$

Now each function has its own variable:

- $X(x)$ is a function for variable $x$ only

- $Y(y)$ function of variable $y$ only

- $Z(z)$ function of variable $z$ only

Now substitute Equation (4) into Equation (3) and divide it by the product: xyz:

$$\frac{d^2 \psi}{dx^2} = YZ \frac{d^2 X}{dx^2} \Rightarrow \frac{1}{X} \frac{d^2 X}{dx^2}$$ $$\frac{d^2 \psi}{dy^2} = XZ \frac{d^2 Y}{dy^2} \Rightarrow \frac{1}{Y} \frac{d^2 Y}{dy^2}$$ $$\frac{d^2 \psi}{dz^2} = XY \frac{d^2 Z}{dz^2} \Rightarrow \frac{1}{Z} \frac{d^2 Z}{dz^2}$$ $$\left( -\frac{\hbar^2}{2mX} \frac{d^2 X}{dx^2} \right) + \left( -\frac{\hbar^2}{2mY} \frac{d^2 Y}{dy^2} \right) + \left( -\frac{\hbar^2}{2mZ} \frac{d^2 Z}{dz^2} \right) = E$$

2

E is an energy constant, and is the sum of $x$, $y$, and $z$. For this to work, each term must equal its own constant. For example,

$$\frac{d^2 X}{d x^2} + \frac{2m}{\hbar^2} \varepsilon_x X = 0$$

Now separate each term in Equation (8) to equal zero:

$$\frac{d^2 X}{d x^2} + \frac{2m}{\hbar^2} \varepsilon_x X = 0$$ $$\frac{d^2 Y}{d y^2} + \frac{2m}{\hbar^2} \varepsilon_y Y = 0$$ $$\frac{d^2 Z}{d z^2} + \frac{2m}{\hbar^2} \varepsilon_z Z = 0$$

Now we can add all the energies together to get the total energy:

$$\varepsilon_x + \varepsilon_y + \varepsilon_z = E$$

Do these equations look familiar? They should because we have now reduced the 3D box into three particles in a 1D box problems!

$$\frac{d^2 X}{d z^2} + \frac{2m}{\hbar^2} E_x X = 0 \approx \frac{d^2 \psi}{d z^2} = - \frac{4 \pi^2}{\lambda^2} \psi$$

Now the equations are very similar to a 1-D box and the boundary conditions are identical, i.e.,

$$n = 1, 2, \dots \infty$$

Use the normalization wavefunction equation for each variable:

$$\psi(x) = \sqrt{2/L_x} \sin n \pi x / L_x$$ $$\text{Limit}: 0 \leq x \leq L$$ $$\psi(x) = 0$$ $$\text{Limit}: L < x < 0$$

Normalization wavefunction equation for each variable

$$X(x) = \sqrt{\frac{2}{L_x}} \sin \left(\frac{n_x \pi x}{L_x}\right)$$ $$Y(y) = \sqrt{\frac{2}{L_y}} \sin \left(\frac{n_y \pi y}{L_y}\right)$$ $$Z(z) = \sqrt{\frac{2}{L_z}} \sin \left(\frac{n_z \pi z}{L_z}\right)$$

The limits of the three quantum numbers

- $n_x = 1,2,3,\dots \infty$

- $n_y = 1,2,3,\dots \infty$

- $n_z = 1,2,3,\dots \infty$

For each constant use the de Broglie Energy equation:

$$\varepsilon_ {z} = \frac {n _ {z} ^ {2} h ^ {2}}{8 m L _ {z} ^ {2}}$$

with $n_z = 1\dots \infty$

Do the same for variables $n_y$ and $n_z$ . Combine Equation 4 with Equations 17-19 to find the wavefunctions inside a 3D box.

$$\psi (\tau) = \sqrt {\frac {8}{V}} \sin \left(\frac {n _ {x} \pi x}{L _ {x}}\right) \sin \left(\frac {n _ {y} \pi y}{L _ {y}}\right) \sin \left(\frac {n _ {z} \pi z}{L _ {z}}\right)$$

with

$$V = \underbrace {L _ {x} \times L _ {y} \times L _ {z}} _ {\text {release of box}}$$

To find the Total Energy, add Equation 20 and Equation 18.

$$E _ {n _ {x}, n _ {y}, n _ {z}} = \frac {h ^ {2}}{8 m} \left(\frac {n _ {x} ^ {2}}{L _ {x} ^ {2}} + \frac {n _ {y} ^ {2}}{L _ {y} ^ {2}} + \frac {n _ {z} ^ {2}}{L _ {z} ^ {2}}\right)$$

The energy of the particle in a 3-D cube (i.e., $a = L, b = L$ , and $c = L$ ) in the ground state is given by Equation 23 with $n_x = 1, n_y = 1$ , and $n_z = 1$ . This energy $(E_{1,1,1})$ is hence

$$E _ {1, 1, 1} = \frac {3 h ^ {2}}{8 m L ^ {2}}$$

The ground state has only one wavefunction and no other state has this specific energy; the ground state and the energy level are said to be non-degenerate. However, in the 3-D cubical box potential the energy of a state depends upon the sum of the squares of the quantum numbers (Equation 21). The particle having a particular value of energy in the excited state MAY has several different stationary states or wavefunctions. If so, these states and energy eigenvalues are said to be degenerate.

For the first excited state, three combinations of the quantum numbers $(n_x, n_y, n_z)$ are $(2, 1, 1)$ , $(1, 2, 1)$ , $(1, 1, 2)$ . The sum of squares of the quantum numbers in each combination is same (equal to 6). Each wavefunction has same energy:

$$E _ {2, 1, 1} = E _ {1, 2, 1} = E _ {1, 1, 2} = \frac {6 h ^ {2}}{8 m L ^ {2}}$$

Corresponding to these combinations three different wavefunctions and three different states are possible. Hence, the first excited state is said to be three-fold or triply degenerate. The number of independent wavefunctions for the stationary states of an energy level is called as the degree of degeneracy of the energy level. The value of energy levels with the corresponding combinations and sum of squares of the quantum numbers

$$n ^ {2} = n _ {x} ^ {2} + n _ {y} ^ {2} + n _ {z} ^ {2}$$

the first five eigenvalues of the energy and the corresponding degenerate energy levels

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