Question #75088

a. The molar heat capacities of a gas at constant pressure
and constant volume are 28.8 J mol−1
K−1
and 20.5 J mol−1
K−1
respectively.
Calculate the gas constant.

Expert's answer

Answer on Question #75088, Physics / Molecular Physics | Thermodynamics

The molar heat capacities of a gas at constant pressure and constant volume are 28.8 J mol1 K128.8\ \mathrm{J\ mol^{-1}\ K^{-1}} and 20.5 J mol1 K120.5\ \mathrm{J\ mol^{-1}\ K^{-1}} respectively. Calculate the gas constant.

Answer:

In the adiabatic process, the adiabatic exponent is


γ=1+RcV\gamma = 1 + \frac{R}{c_V}


We know the adiabatic index


γ=cpcV\gamma = \frac{c_p}{c_V}


We compare these two equations


cpcV=1+RcV\frac{c_p}{c_V} = 1 + \frac{R}{c_V}


We get


R=cpcVR = c_p - c_VR=28.8 J mol1 K120.5 J mol1 K1=8.3 J mol1 K1R = 28.8\ \mathrm{J\ mol^{-1}\ K^{-1}} - 20.5\ \mathrm{J\ mol^{-1}\ K^{-1}} = 8.3\ \mathrm{J\ mol^{-1}\ K^{-1}}

Answer: $8.3\ \mathrm{J\ mol^{-1}\ K^{-1}}$

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