Question #66754

One molelse of an ideal gas expand isothermally to five times its volume. Calculate the entropy change in terms of R , the gas constant.

Expert's answer

Answer on Question #66754– Physics – Molecular Physics – Thermodynamics

One molele of an ideal gas expand isothermally to five times its volume. Calculate the entropy change in terms of RR, the gas constant.

Solution

The entropy of one mole an ideal gas is


S(T,V)=CVlnT+RlnV+S0.S(T, V) = C_V \ln T + R \ln V + S_0.


Entropy change is given by


ΔS=S(T2,V2)S(T1,V1)=CVlnTCVlnT+RlnV2RlnV1=RlnV2V1.\Delta S = S(T_2, V_2) - S(T_1, V_1) = C_V \ln T - C_V \ln T + R \ln V_2 - R \ln V_1 = R \ln \frac{V_2}{V_1}.ΔS=Rln513.37JK.\Delta S = R \ln 5 \approx 13.37 \frac{\mathrm{J}}{\mathrm{K}}.


**Answers**: ΔS=13.37JK\Delta S = 13.37 \frac{\mathrm{J}}{\mathrm{K}}.

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