Question #59640

1. An unbreakable meteorological balloon is released from the ground.Ground level pressure is 98.5 KPa and the temperature is 18.0 Celsius. The balloon contains 74.0 liters of Hydrogen gas. As the balloon soars up, the pressure drops to 27.0 KPa. What is the new volume of the balloon, assuming no temperature change?
2. Re-read question 1, but considering in the real world when you go up in altitude the temperature does change. what is the actual volume of the meteorological balloon if the temp also drops 79.0 celsius from its original temperature?
1

Expert's answer

2016-05-05T09:20:02-0400

Question #59640, Physics, Molecular Physics

1. An unbreakable meteorological balloon is released from the ground. Ground level pressure is 98.5 KPa and the temperature is 18.0 Celsius. The balloon contains 74.0 liters of Hydrogen gas. As the balloon soars up, the pressure drops to 27.0 KPa. What is the new volume of the balloon, assuming no temperature change?

2. Re-read question 1, but considering in the real world when you go up in altitude the temperature does change. what is the actual volume of the meteorological balloon if the temp also drops 79.0 celsius from its original temperature?

Answer:

1. pV=vRTpV = vRT

The only parameter, which was not changed, is the amount of Hydrogen.


v=pVRTV=vRTpv = \frac{pV}{RT} \quad V = \frac{vRT}{p}R=8314.472 kPacm3/(molK)R = 8314.472\ \mathrm{kPa \cdot cm^3 / (mol \cdot K)}v=98.5740008314.3(18+273)=3 molesv = \frac{98.5 \cdot 74000}{8314.3 \cdot (18 + 273)} = 3\ \text{moles}V=38314.3(18+273)27=269962 cm3=270 lV = \frac{3 \cdot 8314.3 \cdot (18 + 273)}{27} = 269962\ \mathrm{cm^3} = 270\ \mathrm{l}


2 T2=18.79=61 C\quad T_{2} = 18.79 = -61\ \mathrm{C}

V=38314.3(61+273)27=195848 cm3=196 lV = \frac{3 \cdot 8314.3 \cdot (-61 + 273)}{27} = 195848\ \mathrm{cm^3} = 196\ \mathrm{l}


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