Question #58707

Calculate the change in internal energy of 2kg of water at
90oC90oC
when it is changed to
3.30m33.30m3
of steam at
100oC100oC
. The whole process occurs at atmospheric pressure. The latent heat of vaporization of water is
2.26×106J/kg2.26×106J/kg
.
4.27 MJ
3.43 kJ
45.72 mJ
543.63 J

Expert's answer

Answer on Question #58707, Physics / Molecular Physics | Thermodynamics |

Calculate the change in internal energy of 2kg2\mathrm{kg} of water at 90C90{}^{\circ}\mathrm{C} when it is changed to 3.30m33.30\mathrm{m}^{3} of steam at 100C100{}^{\circ}\mathrm{C}. The whole process occurs at atmospheric pressure. The latent heat of vaporization of water is 2.26×106J/kg2.26\times 10^{6}\mathrm{J / kg}.

4.27 MJ

3.43 kJ

45.72 mJ

543.63 J

Solution:

The amount of heat received by water is equal to the sum of the change in internal energy of water and the work on the steam:


Q=ΔU+WQ = \Delta U + W


where


Q=Qheat+QvaporQ = Q _ {h e a t} + Q _ {v a p o r}Qheat=CmΔTQ _ {h e a t} = C m \Delta TQvapor=rmQ _ {v a p o r} = r m


where rr is the latent heat of vaporization of water.

The work is


W=pΔV=p(Vsteammρ)W = p \Delta V = p \left(V _ {s t e a m} - \frac {m}{\rho}\right)


where ρ=1000kg/m3\rho = 1000\mathrm{kg / m^3} is the density of water.

The change of the internal energy is


ΔU=QW=CmΔT+rmpΔV==42002(10090)+2.2610621105(3.3021000)=4274200J=4.27MJ\begin{array}{l} \Delta U = Q - W = C m \Delta T + r m - p \Delta V = \\ = 4 2 0 0 \cdot 2 \cdot (1 0 0 - 9 0) + 2. 2 6 \cdot 1 0 ^ {6} \cdot 2 - 1 \cdot 1 0 ^ {5} \left(3. 3 0 - \frac {2}{1 0 0 0}\right) = 4 2 7 4 2 0 0 J = 4. 2 7 M J \\ \end{array}

Answer: 4.27 MJ.

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