Answer on Question #50648, Physics, Molecular Physics | Thermodynamics |
Question
Explain the working of a constant volume gas thermometer with the help of a neat and labelled diagram.
Answer
The schematic diagram of a constant-volume gas thermometer is shown in Fig.1. The volume of an ideal gas in the sensing bulb D is kept constant by adjusting the level of mercury in the arm B of the manometer. The arm B and the arm A are connected by a flexible tube to form a U-tube manometer. The arm B is also connected to the gas bulb D via a capillary tube C, while the other arm A of the manometers is open to atmosphere and can be moved vertically to adjust the mercury level, so the mercury just touches the mark L of the capillary. The pressure in the bulb b is used as a thermometric property and can be given by
where is atmospheric pressure; is the density of the mercury; is the mercury column in manometer.
The gas bulb D is first placed in constant-temperature bath at the triple point temperature of water and the level of mercury is adjusted to touch the mark L by moving the manometer arm A up and down.
Fig.1
As the volume of the bulb becomes constant and the height difference of the mercury in the two arms is recorded as the pressure, corresponding to the mercury column at the triple point is calculated by Eq. (1)
Now the bulb is brought in contact with a system whose temperature , is to be measured. Again, in a similar manner, by keeping the volume of gas in the bulb constant, the height difference of the mercury in the two arms is recorded and the corresponding new pressure is calculated by Eq. (2).
From the ideal gas equation, the new temperature is given by
where is the triple point temperature of water.
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