Question #43120

find the magnitude and ratio of internal energies for 5moles of mono-atomic gas to the di-atomic gas at temperature 27c

Expert's answer

Answer on Question #43120 – Physics – Molecular Physics | Thermodynamics

Question.

Find the magnitude and ratio of internal energies for 5 moles of mono-atomic gas to the di-atomic gas at temperature 27°C.

Given:

ν=5\nu = 5 moles

T=27C=300 KT = 27{}^{\circ}C = 300\ K

Find:

U1=? U2=?U_{1} = ?\ U_{2} = ?

U2U1=?\frac{U_{2}}{U_{1}} = ?

Solution.

From the thermodynamics it’s known that internal energy is:


U=i2νRTU = \frac{i}{2} \nu R T

ii is the number of degrees of freedom;

R=8.31JmoleKR = 8.31 \frac{J}{mole \cdot K} is the gas constant.

For monoatomic gas i=3i = 3, for diatomic gas i=5i = 5.

So,


U1=32νRT; U2=52νRTU_{1} = \frac{3}{2} \nu R T;\ U_{2} = \frac{5}{2} \nu R T


Calculate:


U1=3258.31300=3212465=18697.5 JU_{1} = \frac{3}{2} 5 \cdot 8.31 \cdot 300 = \frac{3}{2} 12465 = 18697.5\ JU2=5258.31300=5212465=31162.5 JU_{2} = \frac{5}{2} 5 \cdot 8.31 \cdot 300 = \frac{5}{2} 12465 = 31162.5\ J


And


U2U1=53\frac{U_{2}}{U_{1}} = \frac{5}{3}


Answer.


U1=32νRT=18697.5JU _ {1} = \frac {3}{2} \nu R T = 1 8 6 9 7. 5 JU2=52νRT=31162.5JU _ {2} = \frac {5}{2} \nu R T = 3 1 1 6 2. 5 JU2U1=53\frac {U _ {2}}{U _ {1}} = \frac {5}{3}


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