Answer on Question #43115 – Physics – Molecular Physics | Thermodynamics
Question.
a quantity 4.3 liter of an ideal gas at pressure 2 atm is compressed adiabatically to volume 1 liter
find
1-the final pressure
2-work done the gas
take gamma constant is 1.4
Given:
V 0 = 4.3 l V_{0} = 4.3\ l V 0 = 4.3 l is the initial volume
P 0 = 2 a t m P_{0} = 2\ atm P 0 = 2 a t m is the initial pressure
V = 1 l V = 1\ l V = 1 l is the final volume
γ = 1.4 \gamma = 1.4 γ = 1.4 is the adiabatic constant
Find:
1) P = ? P = ? P = ? the final pressure
2) A = ? A = ? A = ? the work done the gas
Solution.
1) The adiabatic process equation:
P V γ = const P V ^ {\gamma} = \text{const} P V γ = const
So,
P 0 V 0 γ = P V γ → P = P 0 ( V 0 V ) γ P _ {0} V _ {0} ^ {\gamma} = P V ^ {\gamma} \rightarrow P = P _ {0} \left(\frac {V _ {0}}{V}\right) ^ {\gamma} P 0 V 0 γ = P V γ → P = P 0 ( V V 0 ) γ
Calculate:
P = 2 ⋅ ( 4.3 1 ) 1.4 = 2 ⋅ 7.7 = 15.4 a t m P = 2 \cdot \left(\frac {4 . 3}{1}\right) ^ {1. 4} = 2 \cdot 7. 7 = 1 5. 4\ atm P = 2 ⋅ ( 1 4.3 ) 1.4 = 2 ⋅ 7.7 = 15.4 a t m
2) By definition work done is:
A = ∫ V 0 V P d V A = \int_{V _ {0}}^{V} P d V A = ∫ V 0 V P d V
In our case,
P = const V γ P = \frac {\text{const}}{V ^ {\gamma}} P = V γ const
But, const = P 0 V 0 γ \text{const} = P_0 V_0^\gamma const = P 0 V 0 γ . Therefore,
P = P 0 V 0 γ V γ P = \frac{P_0 V_0^\gamma}{V^\gamma} P = V γ P 0 V 0 γ
Calculate the integral to define the work done:
A = ∫ V 0 V P d V = P 0 V 0 γ ∫ V 0 V d V V γ = P 0 V 0 γ 1 1 − γ 1 V γ − 1 ∣ V 0 V = P 0 V 0 γ 1 − γ ( 1 V γ − 1 − 1 V 0 γ − 1 ) = = P 0 V 0 1 − γ ( ( V 0 V ) γ − 1 − 1 ) \begin{aligned}
A &= \int_{V_0}^V P \, dV = P_0 V_0^\gamma \int_{V_0}^V \frac{dV}{V^\gamma} = P_0 V_0^\gamma \frac{1}{1 - \gamma} \frac{1}{V^{\gamma-1}} \Big|_{V_0}^V = \frac{P_0 V_0^\gamma}{1 - \gamma} \left( \frac{1}{V^{\gamma-1}} - \frac{1}{V_0^{\gamma-1}} \right) = \\
&= \frac{P_0 V_0}{1 - \gamma} \left( \left( \frac{V_0}{V} \right)^{\gamma-1} - 1 \right)
\end{aligned} A = ∫ V 0 V P d V = P 0 V 0 γ ∫ V 0 V V γ d V = P 0 V 0 γ 1 − γ 1 V γ − 1 1 ∣ ∣ V 0 V = 1 − γ P 0 V 0 γ ( V γ − 1 1 − V 0 γ − 1 1 ) = = 1 − γ P 0 V 0 ( ( V V 0 ) γ − 1 − 1 )
Calculate:
A = 2 ⋅ 4.3 1 − 1.4 ( ( 4.3 1 ) 1.4 − 1 − 1 ) = − 8.6 0.4 ( 7.7 − 1 ) = − 21.5 ⋅ 6.7 = − 144 atm ⋅ l 1 atm = 101300 Pa ; 1 l = 1 0 − 3 m 3 \begin{aligned}
A &= \frac{2 \cdot 4.3}{1 - 1.4} \left( \left( \frac{4.3}{1} \right)^{1.4 - 1} - 1 \right) = - \frac{8.6}{0.4} (7.7 - 1) = -21.5 \cdot 6.7 = -144 \, \text{atm} \cdot l \\
&\quad 1 \, \text{atm} = 101300 \, \text{Pa}; \, 1 \, l = 10^{-3} \, \text{m}^3
\end{aligned} A = 1 − 1.4 2 ⋅ 4.3 ( ( 1 4.3 ) 1.4 − 1 − 1 ) = − 0.4 8.6 ( 7.7 − 1 ) = − 21.5 ⋅ 6.7 = − 144 atm ⋅ l 1 atm = 101300 Pa ; 1 l = 1 0 − 3 m 3 A = − 144 atm ⋅ l = − 144 ⋅ 101300 ⋅ 1 0 − 3 = 14587 Pa ⋅ m 3 = 14587 J = 14.587 k J A = -144 \, \text{atm} \cdot l = -144 \cdot 101300 \cdot 10^{-3} = 14587 \, \text{Pa} \cdot \text{m}^3 = 14587 \, J = 14.587 \, kJ A = − 144 atm ⋅ l = − 144 ⋅ 101300 ⋅ 1 0 − 3 = 14587 Pa ⋅ m 3 = 14587 J = 14.587 k J
Answer.
1)
P = P 0 ( V 0 V ) γ = 15.4 atm P = P_0 \left( \frac{V_0}{V} \right)^\gamma = 15.4 \, \text{atm} P = P 0 ( V V 0 ) γ = 15.4 atm
2)
A = P 0 V 0 1 − γ ( ( V 0 V ) γ − 1 − 1 ) = 14587 J = 14.587 k J A = \frac{P_0 V_0}{1 - \gamma} \left( \left( \frac{V_0}{V} \right)^{\gamma-1} - 1 \right) = 14587 \, J = 14.587 \, kJ A = 1 − γ P 0 V 0 ( ( V V 0 ) γ − 1 − 1 ) = 14587 J = 14.587 k J
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