Question #40043

A gas has a volume of 2.50L. When the sample is cooled in ice water at T = 0.00 Celcius, the volume decreases to 2.45 L. What was the initial temperature of the gas?

Expert's answer

Answer on Question#40043-Chemistry-Other

Question

A gas has a volume of 2.50 L. When the sample is cooled in ice water at T = 0.00 Celcius, the volume decreases to 2.45 L. What was the initial temperature of the gas?

Solution

According to the combined gas law or general gas equation:


p1V1T1=p2V2T2\frac {p _ {1} V _ {1}}{T _ {1}} = \frac {p _ {2} V _ {2}}{T _ {2}}


It is given that V1=2.50LV_{1} = 2.50 \, \text{L}, V2=2.45LV_{2} = 2.45 \, \text{L}, T2=0.00C=273.15KT_{2} = 0.00{}^{\circ} \text{C} = 273.15 \, \text{K}.

Since the other is not specified, we can assume p1=p2p_1 = p_2 and thus:


V1T1=V2T2\frac {V _ {1}}{T _ {1}} = \frac {V _ {2}}{T _ {2}}


Hence


T1=T2V1V2=273.152.502.45=278.72KT _ {1} = \frac {T _ {2} V _ {1}}{V _ {2}} = \frac {273.15 \cdot 2.50}{2.45} = 278.72 \, \text{K}


Answer: 278.72 K

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