A gas is suddenly compressed to 10 times 3 its original pressure. Calculate the rise in temperature of the gas if its initial temperature is 27∘C(γ=1.5).
Solution
Sudden compression means there is hardly any time for heat exchange to occur with the environment which indicates that the process is adiabatic for which (P∗Vγ) is constant and γ is adiabatic index.
Also, for an ideal gas,
PV=νRT→V=PνRT,
where P – pressure, V – volume, T – temperature, R – the gas constant, ν – amount of substance.
The initial value of (P∗Vγ) is equal to its final value:
P1∗V1γ=P2∗V2γ.
Then
P1∗(P1νRT1)γ=P2∗(P2νRT2)γ→(T1T2)γ=(P1P2)γ−1.
So
T1T2=(P1P2)γγ−1.
The rise in temperature of the gas
ΔT=T2−T1=T1∗(P1P2)γγ−1−T1=T1((P1P2)γγ−1−1)ΔT=(27+273)K∗((103)1.51.5−1−1)=300K∗((103)31−1)=300K∗(10−1)=2700K.
Answer: 2700K.