Question #35929

a) Two 50 g ice cubes are dropped into 200 g of water in a thermally insulated container. if the water is initially at 25 C, and the ice comes directly from a freezer at -15 c ,what is the final temperature at thermal equilibrium?
b)what is the final temperature if only one ice cube is used?

Expert's answer

a.

Let us write down conservation energy condition. On the left side is heat given to ice cubes, on the right - heat taken from water

2miceciceΔT0+2miceλ+2micecwatert1=mwatercwater(25t1)2\cdot m_{ice}\cdot c_{ice}\cdot\Delta T_{0}+2\cdot m_{ice}\cdot\lambda+2\cdot m_{ice}\cdot c_{water}\cdot t_{1}=m_{water}\cdot c_{water}(25-t_{1})

here cc denotes specific heat capacity and lambda denotes specific heat of melting of ice, ΔT0=15\Delta T_{0}=15{}^{\circ} C. We can find t1t_{1} - the final temperature from this equation.

t1=mwatercwater252miceciceΔT02miceλmwatercwater+2micecwatert_{1}=\frac{m_{water}\cdot c_{water}\cdot 25-2\cdot m_{ice}\cdot c_{ice}\cdot\Delta T_{0}-2\cdot m_{ice}\cdot\lambda}{m_{water}\cdot c_{water}+2\cdot m_{ice}\cdot c_{water}}

But if we evaluate

mwatercwater252miceciceΔT02miceλ=0.242002520.0515206020.05335000=15500m_{water}\cdot c_{water}\cdot 25-2\cdot m_{ice}\cdot c_{ice}\cdot\Delta T_{0}-2\cdot m_{ice}\cdot\lambda=0.2\cdot 4200\cdot 25-2\cdot 0.05\cdot 15\cdot 2060-2\cdot 0.05\cdot 335000=-15500

we will see it is negative. this means that there is not enough heat to melt all the ice. Hence, final temperature is 0 C.

b.

The same formula without factor 2 for ice

t1=(mwatercwater25miceciceΔT0degreesmiceλ)/(mwatercwater+micecwater)=t_{1}=(m_{water}\cdot c_{water}\cdot 25-m_{ice}\cdot c_{ice}\cdot\Delta T_{0}degrees-m_{ice}\cdot\lambda)/(m_{water}\cdot c_{water}+m_{ice}\cdot c_{water})=

=0.24200250.051520600.053350000.24200+0.054200=2.5C=\frac{0.2\cdot 4200\cdot 25-0.05\cdot 15\cdot 2060-0.05\cdot 335000}{0.2\cdot 4200+0.05\cdot 4200}=2.5{}^{\circ}C

Here answer is 2.5 degrees C

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