Question #299152

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1
Expert's answer
2022-02-20T15:47:59-0500

We know that ideal gas equation

PV=nRTPV=nRT

P=constant differentiate with respect T

(dVdT)p=RP(\frac{dV}{dT})_p=\frac{R}{P}

V constant differentiate with respect to T

(dPdT)V=RV(\frac{dP}{dT})_V=\frac{R}{V}

Now We know that

cp=[dQdT]pc_p=[\frac{dQ}{dT}]_p

CpCv=T[dpdT]v[dVdT]pC_p-C_v=T[\frac{dp}{dT}]_v[\frac{dV}{dT}]_p

Assume

Cv=0C_v=0

Cp=T[dpdT]v[dVdT]pC_p=T[\frac{dp}{dT}]_v[\frac{dV}{dT}]_p

We know that

[dpdT]v=[dpdT]s[\frac{dp}{dT}]_v=[\frac{dp}{dT}]_s

Cp=T[dpdT]s[dVdT]pC_p=T[\frac{dp}{dT}]_s[\frac{dV}{dT}]_p

Hance proved


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