Question #28920

calculate the entropy change for 2 mole of ice.Freezing point of water is 273 k and molar enthalpy for fashion is 6 KJ Mole^-1.

Expert's answer

Calculate the entropy change for 2 mole of ice. Freezing point of water is 273k273\,\mathrm{k} and molar enthalpy for fashion is 6 KJ Mole^{\wedge}-1.

Entropy is a mathematically-defined thermodynamic quantity that helps to account for the flow of energy through a thermodynamic process. Entropy was originally defined for a thermodynamically reversible process as:


ΔS=dQrevT\Delta S = \int \frac{dQ_{rev}}{T}


where the uniform temperature (T)(T) of a closed system is divided into an incremental reversible transfer of heat energy into that system (dQrev)(dQ_{rev}).

Therefore:


ΔS=dQ273K=Lv273K\Delta S = \int \frac{dQ}{273\,K} = \frac{Lv}{273\,K}


L - enthalpy for fashion

vv - amount of ice


ΔS=2mole6KJmole273K=12KJ273K=44JK\Delta S = \frac{2\,\mathrm{mole} \cdot \frac{6\,KJ}{\mathrm{mole}}}{273\,K} = \frac{12\,KJ}{273\,K} = 44\,\frac{J}{K}


Answer: ΔS=44JK\Delta S = 44\,\frac{J}{K}

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