We know that
Thermodynamics first law
"dQ=dU+PdV"
"dQ=50\\times4.2+1\\times RT"
"dQ=50\\times4.2+1\\times 8.31T"
"dQ=210+ RT"
Work
"W=PdV"
PdV=nRT
"W=PdV=RT=8.31T J"
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