a)
TfTi=PiPf1.4−11.4Tf800=7001000.2857Tf=1394.87 C\frac{T_f}{T_i} = \frac{P_i}{P_f}^{\frac{1.4-1}{1.4}} \\ \frac{T_f }{ 800} = \frac{700}{100}^{0.2857} T_f= 1394.87 \;CTiTf=PfPi1.41.4−1800Tf=1007000.2857Tf=1394.87C
b) no. of moles =massmolar mass=80 gm29=2.76= \frac{mass}{ molar \;mass}= \frac{80\; gm }{ 29} = 2.76=molarmassmass=2980gm=2.76
R =8.314 J/mol⋅K= 8.314 \;J /mol \cdot K=8.314J/mol⋅K
W=nR(T2−T1)1−1.4=2.76×8.314868.02 K0.4=4.98×104 JW= nR \frac{( T_2-T_1) }{ 1- 1.4}= 2.76 \times 8.314 \frac{ 868.02 \;K }{0.4}=4.98 \times 10^4 \;JW=nR1−1.4(T2−T1)=2.76×8.3140.4868.02K=4.98×104J
c) change in internal energy = - ve (of work done)
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