A vessel of volume 0.2m3 contains nitrogen at 1.013 bar and 15°C. If 0.2 kg of nitrogen is now pumped into the vessel, calculate the new pressure when the vessel has returned to its initial temperature. The molar mass of nitrogen is 28 kg/K - mol and it may be assumed to be a perfect gas.
Solution.
"V=0.2m^3;"
"p_1=1.013\\sdot10^5Pa;"
"T=288K;"
"m_2=0.2kg;"
"M=28\\sdot10^{-3}kg\/mol;"
"p_2V=\\dfrac{m_2}{M}RT\\implies p_2=\\dfrac{m_2RT}{MV};"
"p_2=\\dfrac{0.2\\sdot8.31\\sdot288}{28\\sdot10^{-3}\\sdot0.2}=0.855\\sdot10^5Pa;"
"p=p_1+p_2;"
"p=1.013\\sdot10^5Pa+0.855\\sdot10^5Pa=1.868\\sdot10^5Pa;"
Answer: "p=1.868" bar.
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