) A 3.65-mol sample of an ideal diatomic gas expands adiabatically from a volume of 0.1210 m3 to 0.750 m3. Initially the pressure was 1.00 atm. Determine: (a) the initial and final temperatures; (b) the change in internal energy; (c) the heat lost by the gas; (d) the work done on the gas. (Assume no molecular vibration.)
Solution:-
(a)
"T_1 = {P_1 V_1\\over nR}"
"T_1 = {0.1210*1\\over 3.65*0.082}"
T1= 0.390008058
And
P1V17/5 = P2V27/5
P2 = 0.777
"T_2= {P_2V_2\\over nR}" = "0.77*0.750\\over 3.65*0.082"
=1.92950217
(b)"\\Delta U =({ 5\\over 2})*1*(T_2-T_1)" = 3.75
(c)
Heat loss "\\implies" "\\Delta Q =0"
(d)
"W = - \\Delta U"
= -3.75
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