According to the First law of thermodynamics:
Q=c∗m∗ΔT, were: Q - heat energy, m - mass (liquid), c - heat capacityΔT=c∗mQ
The greater rise in temperature had a liquid with a smaller heat capacity or (and) smaller mass.
The smaller heat capacity and smaller mass have ethanol:
C(ethanol)=2.46C(water)=4,183M(100ml ethanol)=0.08 KgM(100ml water)=0.1 Kg
Ethanol experiences the greater rise in temperature.
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