The horizontal range of a projectile is "d = \\frac{v^2 sin 2\\theta}{g}".
For a fixed "v" and "g", in order to maximize "d", we need to maximize "\\sin 2 \\theta". Since "\\sin x" attains its maximum value at "x = \\frac{\\pi}{2}", "\\sin 2 \\theta" is maximized at "\\theta = \\frac{\\pi}{4}".
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