The kinetic energy of the moving particles is completely transformed into electric potential energy at the point of closest approach.
Ue=Kk(e)(2e)r2=12(m)v2+12(4m)v2U_e = K\\ \frac{k(e)(2e)}{r^2} = \frac12 (m)v^2 + \frac12 (4m)v^2Ue=Kr2k(e)(2e)=21(m)v2+21(4m)v2
r=4ke25mv2r=\frac{4ke^2}{5mv^2}r=5mv24ke2
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