Calculate the molar mass of a liquid if 0.995g if it’s vapour occupy 250L at 200 degree cent and 45.0Torr
m=0.995 gV=250 LT=200=473 Kp=45.0 Torr=0.0592 atmm=0.995 \; g \\ V = 250 \;L \\ T = 200 = 473 \; K \\ p=45.0 \;Torr = 0.0592 \; atmm=0.995gV=250LT=200=473Kp=45.0Torr=0.0592atm
Ideal Gas Law
pV =nRT
R = 0.08206 L×atm/mol×K
n=pVRTn=0.0592×2500.08206×473=0.381 molM=mnM=0.9950.381=2.61 g/moln = \frac{pV}{RT} \\ n = \frac{0.0592 \times 250}{0.08206 \times 473} = 0.381 \; mol \\ M = \frac{m}{n} \\ M = \frac{0.995}{0.381} = 2.61 \; g/moln=RTpVn=0.08206×4730.0592×250=0.381molM=nmM=0.3810.995=2.61g/mol
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