2011-04-19T08:15:44-04:00
Evaluate the Rydberg constant R using Bohr theory and show that its value is R = 1.0974x10-1.
1
2011-06-22T06:41:25-0400
The energy of electron in atom E=(mV2 )/2-(Ze2 )/(4πε0 r.) (1) The balance of forces (Ze2 )/(4πε0 r2 )=(mV2 )/r (2) From here we get E=-(Ze2 )/(8πε0 r.) (3) Multiplying (2) by mr^3 and using L=nħ we get (Ze^2 mr)/(4πε_0 )=(mVr)^2=n^2 ħ^2 And finally E=-(Ze^4 m)/(32 ε_0^2 π^2 n^2 ħ^2.) Then hν=(Ze4 m)/(32 ε_02 π2 ħ2 )(1/(n1 2 )-1/(n2 2 )) but as we know from atomic physics hν=hcR(1/(n1 2 )-1/(n2 2 ))R = (Ze4 m)/(32ε0 2 π2 ħ3 c) = 1.0974
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