An electrochemical cell consists of pure cadmium immersed in a solution of Cd2+ ions and pure nickel in a solution of Ni2+ ions. Assume that the standard electrode potentials for Ni and Cd are –0.250 V and –0.403 V, respectively.
- If the cell is a standard one (ie, 1 M solution for both ions at 25 °C):
- Which electrode will be oxidised and which electrode will be reduced? [2]
- Write the oxidation reaction, reduction reaction, and overall electrochemical reaction. [2]
- Calculate the standard voltage that is generated. [2]
- If the concentrations of Cd2+ and Ni2+ ions are 0.3 M and 10-4 M respectively, compute the cell potential at 25 °C.
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