Question #192690

what is the enthalpy of a gas at 20 K given that its heat capacity as a function of temperature is given by C=2T^2, over the range T= 0K to 20K ?


1
Expert's answer
2021-05-18T13:53:44-0400

At constant pressure, the heat capacity is


CP=dHdTC_P=\dfrac{dH}{dT}


Then

dH=CPdTdH=C_PdT

Integrate both sides


ΔH=TiTfCPdT\Delta H=\displaystyle\int_{T_i}^{T_f}C_PdT



Given CP=2T2,Ti=0K,Tf=20KC_P=2T^2, T_i=0K, T_f=20K



ΔH=0202T2dT=[2T33]200\Delta H=\displaystyle\int_{0}^{20}2T^2dT=\bigg[\dfrac{2T^3}{3}\bigg]\begin{matrix} 20 \\ 0 \end{matrix}

=163×103 J=\dfrac{16}{3}\times10^3 \ J


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