6. Gas fills a cylinder fitted with a frictionless piston. The initial pressure and volume are 40 MPa and 0.05 dm3 respectively. The gas expands reversibly and polytropically to 0.5 MPa and 1 dm3 respectively. Calculate the index of expansion and the work done.
p1 =40MPa
V1 =0.05dm3
p2 =0.5MPa
V2 =1dm3
p1V1n = p2V2n
(40/0.5) = (1/0.05)n
80 = 20n
n = 1.463
W=p2V2-P1V1/n-1
=(0.5x106)x(1x10-3)−(40x106)x(0.05x10-3)/0.463
=-3.24KJ
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