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The density of steam at 1 atm is 0.6 kg/m³, then specific volume of steam at this


pressure is

Calculate ∆G and ∆S when 1 mole of ethanol is vaporized at 65◦C and 1 atm pressure. The latent heat of vaporization of 1g of ethanol is 200 cal

OLED is the one which?

Find the equilibrium constant for the reaction called the water-gas reaction


H2+CO2<--->H2O+CO


at 1200 K

Find values for residual enthalp and entropy for n-butane gas at 500K and 5 bar as given by redlich kwong equation


Chemical P was fed into a CSTR reactor to react with an excess amount of chemical Q to produce chemical R. However, during the reaction, chemical S was also produced by conversion of chemical R. The reactions involve liquids and follow elementary rate law as follow:

 

P + Q → R (1)

R → S (2)

 

The reaction rate constant for chemical P for the first reaction was given as 4 dm3mol-1s-1, while the reaction rate constant for chemical R for the second reaction was given as 6 dm3mol-1s-1. The entering concentration of chemical P was 10 mol dm-3. Answer the following questions using the given information.

 

a) Write the net rate law for chemical P, R and S. (6 Marks)

 

b) Write the concentration of chemical P, R and S in terms of space time. (14 Marks)

 

 

As a new engineer in a company XZ, your boss has assigned you a project that is related to the removal of pollutant A in pharmaceutical wastewater. To achieve the objective of the project, you had conducted the experiment in a batch mode. The initial concentration of the pollutant A was set at 2.5 mol/dm3. The remaining concentration of the pollutant was identified using a UV-Vis. The complete experimental data obtained is tabulated in Table 1.


Table 1


t (hr) 5 10 15 20 25



A (mol/dm3) 1.95 1.65 1.15 0.88 0.60


a.Determine the removal rate of pollutant A by using numerical method. (15 Marks)


b.Is the removal time of 25 hours sufficiently enough to remove the pollutant A more than 90%? Justify your answer by using answer from (a). (5 Marks)


 The irreversible gas phase reaction A + B --® 2C

is carried out in a PBR. The reaction rate is given as -rA = kCA. The feed is equal molar in A and B and the weight of the catalyst used is 15 kg.

Additional information FA0 = 100 mol/s

k = 1 dm3/kg.s CA0 = 1 mol/dm3

a = 0.064 kg-1

 

Determine the conversion exiting the reactor.


A first-order, irreversible liquid-phase reaction is taking place in a CSTR and 60% conversion is obtained. What is the minimum number of CSTR of the same size needed to place downstream in series to achieve 90% of total conversion.


Liquid A decomposes by first-order kinetics, and in a batch reactor 50% of A is converted in a 5-minute run. How much longer would it take to reach 75% conversion?


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