Answer on Question #99054 – Chemistry – Other
Task:
Calculate the [H3O+], [OH-], pH, and pOH for a solution prepared by dissolving 3.1g KOH(s) (FW=56 g/mol) unto enough water to give a volume of 0.500L.
Solution:
1) Find the molar concentration of the KOH:
Cm = n/V = m / (M*V).
Then,
C(KOH) = m(KOH) / (M(KOH)*V) = 3.1 / (56*0.5) = 3.1 / 28 = 0.1107 (mol/L).
2) dissociation reaction of KOH:
KOH = K+ + OH-;
KOH is strong electrolyte. Then,
C(KOH) = [OH-] = 0.1107 mol/L;
3)pOH = -log[OH-] = 0.96;
pOH = 0.96.
4) pOH + pH = 14;
pH = 14- pOH = 14 - 0.96 = 13.04;
pH = 13.04.
5) pH = -log[H3O+];
[H3O+] = 10-pH = 9.12*10-14 mol/L;
[H3O+] = [H+] = 9.12*10-14 mol/L.
Answer: [H3O+] = 9.12*10-14 mol/L ; [OH-] = 0.1107 mol/L; pH = 13.04; pOH = 0.96.
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