Molarity/concentration is moles/ltr.
so,1.25 M "Na_3P" means 1.25 moles of "Na_3P" in one litre of solution.
"Na_3P \\to 3Na^++P^-"
This implies,
1 mole of Na3P means 3 mole of Na+
1.25 M Na3P means "3 \\times 1.25 =3.75" moles of Na+ per litre of solution.
Hence 3.75 moles of Na+ are present in per litre of solution.
Concentration of Na+ ions is 3.75 mol/L in the solution.
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