CaCO3 --> CaO + CO2
According to ideal gas law:
PV=nRT
Vm=n/V=RT/P
Volume of ideal gas at STP is equal to 22.4L for 1 mol.
Vm=22.4 L/mol
n(CO2)=V(CO2)/Vm
n(CO2)=0.4/22.4=0.018mol
n(CO2):n(CaCO3)=1:1
n(CaCO3)=0.018 mol
m(CaCO3)=n(CaCO3)*M(CaCO3)
m(CaCO3)=0.018*100=1.8g
Answer: m(CaCO3)=1.8g
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