According to the ideal gas law:
"V = nRT\/p"where V is a volume, n is a number of moles, R is a gas constant (0.0821 L∙atm/K∙mol), T is a temperature, p is a pressure.
As 685 mmHg = 0.9 atm:
V = 0.86 mol × 0.0821 L∙atm/K∙mol × 253.5 K / 0.9 atm = 19.9 L
Answer: 19.9 L
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