Compounds that have stronger intermolecular forces have higher boiling point.
The boiling point increases:
CH3-CH2-CH3 < CH3-O-CH3 < CH3-CH2-OH.
Intermolecular forces:
CH3-CH2-CH3: dispersion forces ;
CH3-O-CH3: dispersion and dipole-dipole forces;
CH3-CH2-OH: dispersion, dipole-dipole and hydrogen forces.
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