Question #81815

Calculate the volume of 0.0500 M EDTA needed to titrate 23.37 mL of 0.0741 M Mg(NO3)2

Expert's answer

Answer on Question #81815 – Chemistry – Other

Task:

Calculate the volume of 0.0500 M EDTA needed to titrate 23.37 mL of 0.0741 M Mg(NO₃)₂.

Solution:

Reagents for EDTA titrations: EDTA, H₄Y and Na₂H₂Y · 2H₂O.

Complexes of EDTA and metal ions (1:1).


Mg2++H2Y2=MgH2YMg^{2+} + H_2Y^{2-} = MgH_2Yn(Mg2+)=n(H2Y2);n(Mg^{2+}) = n(H_2Y^{2-});C=nV;n=CVC = \frac{n}{V}; \Rightarrow n = C*VC(Mg2+)V(Mg2+)=C(H2Y2)V(H2Y2);C(Mg^{2+}) * V(Mg^{2+}) = C(H_2Y^{2-}) * V(H_2Y^{2-});0.0741M23.37mL=0.0500MV(H2Y2);0.0741M * 23.37 \, \text{mL} = 0.0500M * V(H_2Y^{2-});V(H2Y2)=0.0741M23.37mL0.0500M=34.63mL;V(H_2Y^{2-}) = \frac{0.0741M * 23.37 \, \text{mL}}{0.0500M} = 34.63 \, \text{mL};V(H2Y2)=34.63mL.V(H_2Y^{2-}) = 34.63 \, \text{mL}.


Answer: 34.63 mL of EDTA.

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