Question #73463

Calculate the volume of 1.01mol/L sodium hydroxide that is required to neutralize 25.00mL of a hydrochloric acid solution that has a pH of 0.32

Expert's answer

Answer on Question #73463 – Chemistry – Other

Task:

Calculate the volume of 1.01mol/L1.01\mathrm{mol/L} sodium hydroxide that is required to neutralize 25.00mL25.00\mathrm{mL} of a hydrochloric acid solution that has a pH\mathsf{pH} of 0.32

Solution:

pH=log[H+]=0.32;[H+]=10pH=100.32=0.47863M;[H+]=C(HCl)=0.47863M.\begin{array}{l} pH = - \log [H^{+}] = 0.32; \\ [\mathrm{H}^{+}] = 10^{-pH} = 10^{-0.32} = 0.47863\,M; \\ [\mathrm{H}^{+}] = C(HCl) = 0.47863\,M. \end{array}


The reaction:


NaOH+HCl=NaCl+H2ONaOH + HCl = NaCl + H_{2}O


By the reaction equation:


n(NaOH)=n(HCl);C(NaOH)V(NaOH)=C(HCl)V(HCl);V(NaOH)=C(HCl)V(HCl)C(NaOH)=0.47863M25.00mL1.01M=11.847;V(NaOH)=11.85mL.\begin{array}{l} n(NaOH) = n(HCl); \\ C(NaOH) * V(NaOH) = C(HCl) * V(HCl); \\ V(NaOH) = \frac{C(HCl) * V(HCl)}{C(NaOH)} = \frac{0.47863\,M * 25.00\,mL}{1.01\,M} = 11.847; \\ V(NaOH) = 11.85\,mL. \end{array}


Answer: V(NaOH)=11.85mLV(NaOH) = 11.85\,mL

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