Question #73294

Derive an expression for calculating energy values corresponding n = 3 for a particle in one dimensional box.

Expert's answer

Answer on Question #73294 - Chemistry – Other

Question

Derive an expression for calculating energy values corresponding n=3n = 3 for a particle in one dimensional box.

Answer:

The energy of a particle in one dimensional box is:


En=n2h28mL2E_n = \frac{n^2 h^2}{8 m L^2}


where nn is quantum number;

h – Planck constant, h=6.6261034h = 6.626 \cdot 10^{-34} J·s;

m – is the mass of particle;

L – length of box.

Then we have:


E3=32h28mL2=9h28mL2E_3 = \frac{3^2 h^2}{8 m L^2} = \frac{9 h^2}{8 m L^2}


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