Question #70767

WHAT IS THE HYDROGEN ION CONCENTRATION OF 0.1N BORIC ACID

A)1.5X10^-12
B)3.7X10^-8
C)4.82X10^-4
D)6.3X10^-6

Expert's answer

Answer on Question #70767 – Chemistry – Other

Task:

What is the hydrogen ion concentration of 0.1 N boric acid.

A) 1.15×10121.15 \times 10^{-12};

B) 3.7×1083.7 \times 10^{-8};

C) 4.82×1044.82 \times 10^{-4};

D) 6.3×1066.3 \times 10^{-6}.

Solution:

The dissociation of boric acid in the first stage proceeds according to the reaction:


H3BO3=H++H2BO3,H_3BO_3^- = H^+ + H_2BO_3^-,


For which the dissociation constant Kd1=5.8×1010K_{d1} = 5.8 \times 10^{-10},


Kd1=[H2BO3][H+][H3BO3]=5.8×1010.K_{d1} = \frac{[H_2BO_3^-] \cdot [H^+]}{[H_3BO_3^-]} = 5.8 \times 10^{-10}.


The second and third stages of dissociation of boric acid are neglected.


[H+]=Kd1Cm=6.3×106.[H^+] = \sqrt{K_{d1} \cdot C_m} = 6.3 \times 10^{-6}.


Answer: D) 6.3×1066.3 \times 10^{-6} mol/dm³.

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