Question #65963

Draw and explain the NMR spectrum of ethanol.

Expert's answer

Answer on Question #65963 - Chemistry - Other

Task:

Draw and explain the NMR spectrum of ethanol.

Solution:

Chemical formula is C2H6O\mathrm{C}_2\mathrm{H}_6\mathrm{O} , which can be written also as C2H5OH\mathrm{C}_2\mathrm{H}_5\mathrm{OH} or CH3CH2OH\mathrm{CH}_3\mathrm{-CH}_2\mathrm{-OH} . Full structural formula of ethanol:



Skeletal formula of ethanol:


1^{1} H NMR spectrum of ethanol:



PPM



d 1.18 is a triplet (methyl group, CH3-\mathrm{CH}_3 );

d 3.59 is a quartet (methylene group, CH2-\mathrm{CH}_2 );

d 4.70 is a singlet (hydroxy group, -OH).

$^{13}$ C NMR spectrum of ethanol:


d 17.4 is a methyl group, CH3-\mathrm{CH}_3 ;

d 57.9 is a methylene group, CH2-\mathrm{CH}_2 .

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