Question #60144

What volume of 0.117 M HCl is needed to neutralize 28.67 mL of 0.137 M Ca(OH)2 ?

Expert's answer

Answer on the question #60144, Chemistry / Other

Question:

What volume of 0.117 M HCl is needed to neutralize 28.67 mL of 0.137 M Ca(OH)₂?

Solution:

Let's write the reaction equation:


2HCl+Ca(OH)22H2O+CaCl22HCl + Ca(OH)_2 \rightarrow 2H_2O + CaCl_2


One can see that 2 moles of hydrochloric acid reacts with 1 mole of calcium hydroxide:


n(HCl)2=n(Ca(OH)2).\frac{n(HCl)}{2} = n(Ca(OH)_2).


The volume of HCl is equal to the ratio of the number of the moles and concentration:


V(HCl)=n(HCl)c(HCl)=2n(Ca(OH)2)c(HCl).V(HCl) = \frac{n(HCl)}{c(HCl)} = \frac{2 \cdot n(Ca(OH)_2)}{c(HCl)}.


In its turn, the number of the moles of calcium hydroxide is the product of its volume and molar concentration:


n(Ca(OH)2)=V(Ca(OH)2)c(Ca(OH)2)=28.67103(L)0.137(molL1),n(Ca(OH)2)=3.928103(mol).\begin{array}{l} n(Ca(OH)_2) = V(Ca(OH)_2) \cdot c(Ca(OH)_2) = 28.67 \cdot 10^{-3}(L) \cdot 0.137\,(\text{mol} \, L^{-1}), \\ n(Ca(OH)_2) = 3.928 \cdot 10^{-3}(\text{mol}). \end{array}


And finally, the volume of hydrochloric acid is:


V(HCl)=23.928103(mol)0.117(molL1)=67.2103L, or 67.14mL.V(HCl) = \frac{2 \cdot 3.928 \cdot 10^{-3}(\text{mol})}{0.117\,(\text{mol} \, L^{-1})} = 67.2 \cdot 10^{-3} \, L, \text{ or } 67.14 \, \text{mL}.


Answer: 67.14 mL

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