Question #58555

The Ka for methanoic acid, the chemical that causes the sting in insect bites, is 1.8 x 10^-4. Calculate the pH of a 0.40 mol/L methanoic acid solution.

Expert's answer

Answer on Question #58555 – Chemistry – Other

Task:

The Ka for methanoic acid, the chemical that causes the sting in insect bites, is 1.8×1041.8 \times 10^{4}–4. Calculate the pH of a 0.40 mol/L methanoic acid solution.

Solution:

The equation of the dissociation of methanoic acid:


HCOOH=H++COOHHCOOH = H^{+} + COOH^{-}


The molar concentration of methanoic acid:


C=0.40mol/lC = 0.40 \, \text{mol/l}


Find the equilibrium concentration of hydrogen ions by the formula:


[H+]=Ka×C\left[ H^{+} \right] = \sqrt{K_{a} \times C}


Where:

- KaK_{a} – dissociation constant;

- CC – the molar concentration.

We get:


[H+]=1.8×104×0.4=7.2×105=0.00848.\left[ H^{+} \right] = \sqrt{1.8 \times 10^{-4} \times 0.4} = \sqrt{7.2 \times 10^{-5}} = 0.00848.


We compute pH by the formula:


pH=lg[H+].pH = -\lg \left[ H^{+} \right].


PH value (pH) of the solution is numerically equal to the negative decimal logarithm of the hydrogen ion concentration in the solution.

We get:


pH=lg[0.00848]=2.07pH = -\lg \left[ 0.00848 \right] = 2.07


Answer: pH=2.07pH = 2.07.


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