Question #51553

If you have 100 g of NaOH and 100 g of Al to perform the reaction, how many grams of H2 will you produce?
6NaOH(aq) + 2Al(s) ® 2NA3AlO3(s) + 3H2(g)

Expert's answer

Answer on Question #51553 - Chemistry – Other

Question

If you have 100 g of NaOH and 100 g of Al to perform the reaction, how many grams of H₂ will you produce?


6NaOH(aq)+2Al(s)=2NA3AlO3(s)+3H2(g)6 \mathrm{NaOH}(aq) + 2 \mathrm{Al}(s) = 2 \mathrm{NA_3AlO_3}(s) + 3 \mathrm{H_2}(g)

Answer:

Molar masses of the reactants equal:


M(NaOH)=40 g/mol,M(Al)=27 g/molM(\mathrm{NaOH}) = 40 \ \mathrm{g/mol}, \quad M(\mathrm{Al}) = 27 \ \mathrm{g/mol}


Number of moles of the reactants are:


n(Al)=m(Al)M(Al)=10027=3.7 moln(Al) = \frac{m(Al)}{M(Al)} = \frac{100}{27} = 3.7 \ \mathrm{mol}n(NaOH)=m(NaOH)M(NaOH)=10040=2.5 moln(\mathrm{NaOH}) = \frac{m(\mathrm{NaOH})}{M(\mathrm{NaOH})} = \frac{100}{40} = 2.5 \ \mathrm{mol}


Then we make a proportion:

- 2 moles of Al react with 6 moles of NaOH

- 3.7 moles of Al – x moles of NaOH


x=3.762=11.1 moles of NaOH should react with 3.7 moles of Alx = \frac{3.7 \cdot 6}{2} = 11.1 \ \mathrm{moles} \ \text{of} \ \mathrm{NaOH} \ \text{should} \ \text{react} \ \text{with} \ 3.7 \ \mathrm{moles} \ \text{of} \ \mathrm{Al}


There are only 2.5 moles of sodium hydroxide, therefore it is the limiting reactant.

We need to make another proportion to calculate the mass of H₂ that could be produced by the chemical reaction:

- 6 moles of NaOH produce 3 moles of H₂

- 2.5 moles of NaOH – x moles of H₂


x=2.536=1.25 moles of H2 could be producedx = \frac{2.5 \cdot 3}{6} = 1.25 \ \mathrm{moles} \ \text{of} \ \mathrm{H_2} \ \text{could} \ \text{be} \ \text{produced}


The mass of H₂ equals:


m(H2)=n(H2)M(H2)=1.252=2.5 gm(H_2) = n(H_2) \cdot M(H_2) = 1.25 \cdot 2 = 2.5 \ g

Answer: 2.5 g of H₂

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