Question #50091

Compute the relative rate of diffusion of phosphine (PH3) to methane (CH4)

Expert's answer

Answer on Question #50051, Chemistry, Other

**Task:**

Compute the relative rate of diffusion of phosphine (PH₃) to methane (CH₄)

**Answer:**

To solve this task a Graham's law must be applied.


Ratediffusion1MM\text{Rate}_{\text{diffusion}} \propto \frac{1}{\sqrt{\text{MM}}}


According to it:


Rate(PH3)2M(PH3)=Rate(CH4)2M(CH4)\frac{\text{Rate} \left( PH_3 \right)^2}{M \left( PH_3 \right)} = \frac{\text{Rate} \left( CH_4 \right)^2}{M \left( CH_4 \right)}M(PH3)=34g/molM \left( PH_3 \right) = 34\,g/molM(CH4)=16g/molM \left( CH_4 \right) = 16\,g/molRate ratio=M(CH4)M(PH3)=1634=0.686\text{Rate ratio} = \sqrt{\frac{M \left( CH_4 \right)}{M \left( PH_3 \right)}} = \sqrt{\frac{16}{34}} = 0.686


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