Question #48868

A NaOH solution is standardized by titration with 0.835 g KHP (monoprotic standard acid, MW = 204.2 g/mol). 23.47 mL of the unknown NaOH solution is needed to titrate the 0.835 g KHP to the endpoint. Calculate the concentration of the NaOH solution.

Expert's answer

Question #48868, Chemistry, Other

A NaOH solution is standardized by titration with 0.835 g KHP (monoprotic standard acid, MW = 204.2 g/mol). 23.47 mL of the unknown NaOH solution is needed to titrate the 0.835 g KHP to the endpoint. Calculate the concentration of the NaOH solution.

Answer:

VNaOH=23.47 mLV_{NaOH} = 23.47 \text{ mL}

mKHP=0.834 gm_{KHP} = 0.834 \text{ g}

MKHP=204.2 g/molM_{KHP} = 204.2 \text{ g/mol}

nNaOH=nKHPn_{NaOH} = n_{KHP}n=cVn = c \cdot Vn=m/Mn = m / McNaOHVNaOH=mKHP/MKHPc_{NaOH} \cdot V_{NaOH} = m_{KHP} / M_{KHP}cNaOH=mKHP/(MKHPVNaOH)c_{NaOH} = m_{KHP} / (M_{KHP} \cdot V_{NaOH})cNaOH=0.834/(204.2×0.02347)=0.1740 mol/Lc_{NaOH} = 0.834 / (204.2 \times 0.02347) = 0.1740 \text{ mol/L}


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