Question #46599

If you have 48.00g of K2CrO4, what volume of 0.1500 M BaCl2 solution is needed to completely react with all the K2CrO4?

Expert's answer

Answer on Question #46599 - Chemistry - Other

Question

If you have 48.00g48.00\mathrm{g} of K2CrO4\mathrm{K}_2\mathrm{CrO}_4 , what volume of 0.1500M0.1500\mathrm{M} BaCl2\mathrm{BaCl}_2 solution is needed to completely react with all the K2CrO4\mathrm{K}_2\mathrm{CrO}_4 ?

Answer:

Balanced reaction equation is:


K2CrO4(s)+BaCl2(aq)=BaCrO4(s)+2KCl(aq)\mathrm {K} _ {2} \mathrm {C r O} _ {4} (\mathrm {s}) + \mathrm {B a C l} _ {2} (\mathrm {a q}) = \mathrm {B a C r O} _ {4} \downarrow (\mathrm {s}) + 2 \mathrm {K C l} (\mathrm {a q})


Molar masses of K2CrO4\mathrm{K}_2\mathrm{CrO}_4 and BaCl2\mathrm{BaCl}_2 equal:


M(K2CrO4)=2M(K)+M(Cr)+4M(O)=239.098+52.996+415.999=195.188gmolM (K _ {2} C r O _ {4}) = 2 M (K) + M (C r) + 4 M (O) = 2 \cdot 3 9. 0 9 8 + 5 2. 9 9 6 + 4 \cdot 1 5. 9 9 9 = 1 9 5. 1 8 8 \frac {g}{m o l}M(BaCl2)=M(Ba)+2M(Cl)=137.327+235.45=208.227gmolM (B a C l _ {2}) = M (B a) + 2 M (C l) = 1 3 7. 3 2 7 + 2 \cdot 3 5. 4 5 = 2 0 8. 2 2 7 \frac {g}{m o l}


Number of moles of K2CrO4\mathrm{K}_2\mathrm{CrO}_4 equals:


n=m(K2CrO4)M(K2CrO4)=48.00195.188=0.246moln = \frac {m (K _ {2} C r O _ {4})}{M (K _ {2} C r O _ {4})} = \frac {4 8 . 0 0}{1 9 5 . 1 8 8} = 0. 2 4 6 m o l


According to reaction equation 1 mol of K2CrO4\mathrm{K}_2\mathrm{CrO}_4 reacts with 1 mol of BaCl2\mathrm{BaCl}_2 , so 0.246 mol of BaCl2\mathrm{BaCl}_2 is needed to completely react with all the K2CrO4\mathrm{K}_2\mathrm{CrO}_4 .

The volume of 0.1500 M BaCl2\mathrm{BaCl}_2 solution needed is:


V=n(BaCl2)C=0.2460.1500=1.64LV = \frac {n (B a C l _ {2})}{C} = \frac {0 . 2 4 6}{0 . 1 5 0 0} = 1. 6 4 L


Answer: 1.64 L


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