Question #45402

how many moles of potassium chlorate to be heated to produce 11.2 litre oxygen ?

Expert's answer

Answer on Question #45402 – Chemistry – Other

Question

How many moles of potassium chlorate to be heated to produce 11.2 litre oxygen?

Solution

Number of moles in 11.2 litres of oxygen:


nO2=VO2Vm=11.2L22.4Lmol=0.5mol,n_{O_2} = \frac{V_{O_2}}{V_m} = \frac{11.2 \, L}{22.4 \, \frac{L}{mol}} = 0.5 \, mol,


where VmV_m – molar volume.

The balanced chemical equation of potassium chlorate thermal decomposition is as follows


2KClO3(s)3O2(g)+2KCl(s)2 \, \mathrm{KClO_3}(s) \rightarrow 3 \, \mathrm{O_2}(g) + 2 \, \mathrm{KCl}(s)


As is clear from the chemical equation, 2 moles of KClO3\mathrm{KClO_3} are to be heated to produce 3 moles of O2\mathrm{O_2}, i.e. molar ratio nKClO3/nO2=2/3n_{\mathrm{KClO_3}} / n_{\mathrm{O_2}} = 2 / 3. Hence


nKClO3=23nO2=20.53=0.33moln_{\mathrm{KClO_3}} = \frac{2}{3} \cdot n_{\mathrm{O_2}} = \frac{2 \cdot 0.5}{3} = 0.33 \, mol

Answer: about 0.33 mole of potassium chlorate is to be heated to produce 11.2 litres of oxygen.

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